Prince led St. Jospeh's to four-straight NCAA Tournaments, including a 2024 National Championship game appearance.
Brunt, who focuses on coaching the defense, led the Nittany Lions to the second-most steals and third in turnovers forced per game in the Big Ten last season.
As a true freshman, Wallace-Coleman did not appear in any games, preserving his redshirt.
Hayes was rated as a four-star recruit out of high school.
Askew is the 14th player to commit to the Nittany Lions this cycle.
The Glenside, Pennsylvania, native appeared in 12 games this season with the Mountaineers, recording 12 tackles and one tackle for loss as a true freshman.