Brockington signed an Exhibit 10 contract after going undrafted in the 2022 NBA Draft.
Coffey led the National Women's Soccer League with the highest passing accuracy percentage in the month of June at 85%.
The Nittany Lions last played in the Gavitt Games in 2019 when they beat Georgetown 81-66.
The Nittany Lions and the Tigers will face off for the first time since 2005.
The Class of 2024 prospect sits at No. 39 in national recruiting rankings.
Harrar is Penn State men's basketball's first to earn the award since 1995, while Parker is women's volleyball's first representative since 2018.