The Nittany Lions topped the Wildcats 38-17 in their last matchup in September 2021.
The Nittany Lions shut out the Panthers 59-0 in the two programs' first and only previous matchup in 2002.
The 2025 season opener will be the first-ever matchup between the two programs.
The two programs have met three times before, with the Nittany Lions on a two-game win streak.
Hart is the second cornerback to join Penn State's 2026 recruiting class.
Urgo will take the reins of his alma mater after being fired by Fordham in March.