Penn State hired Iowa State safeties coach Deon Broomfield on December 11.
Mack earned starting safety reps early in the season.
Payne has made appearances in the last three seasons for the Nittany Lions.
Boyer played in seven games this season.
Rucci started 18 games across two seasons for the Nittany Lions.
Malloe coached alongside new defensive coordinator D'Anton Lynn at UCLA in 2023.