Their matchup with the Wolfpack marks the second announced non-conference game for the Nittany Lions in 2025 thus far.
Palko, who was originally committed to Bucknell, visited Penn State and received an offer earlier this week.
Under Pennsylvania House Bill 2633, Penn State can now legally work with its student-athletes to secure NIL deals.
"Myself and the Penn State community are definitely ready to see something new. I'm with them."
The Nittany Lions continue moving up the rankings, leaping forward three spots.
After citing frustrations with "misreporting," James Franklin revealed Porter is expected to return this season.