The Nittany Lions outscored the Scarlet Knights 43-32 in the second half, but it wasn't enough to complete the comeback.
Starck was named Big Ten Freshman of the Year earlier this week.
Jess Mruzik's 21 kills and outstanding defensive showing elevated the Nittany Lions to the third round.
Penn State remains undefeated in conference play.
Penn State suffered through miscues on both sides of the ball to drop its second consecutive game.
