The Nittany Lions suffered their fourth defeat of the season Saturday, dropping a rescheduled away match to Villanova 2-1.
No. 13 Penn State (1-0) will face off with Pitt for the 99th time in program history on Saturday night.
In a showdown between seven-time national champions, Stanford swept the Nittany Lions 25-23, 25-20, 25-20 in Big Ten/Pac-12 Challenge action.
The 32-year old star who gained fame for a number of jams in the mid-2000s brought back some nostalgia for the crowd, mixing in his more famous songs alongside covers of other notable singles from the era.
Cuylle committed to Penn State on June 5, but he must forfeit his NCAA eligibility after signing with Windsor on Thursday.
Aurelia Meijer finished the game with four points, and two other Nittany Lions scored their first career goals in a dominant home victory.